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Wednesday, October 28, 2009

For a first order reaction the rate R = N?

so the ratio of rates at two different times is given by R(t1)/R(t2) = N(t1)/N(t2).



For nuclear decay the rate is ofen is expressed in units of counts per unit of time.



A chemists determines that a sample of petrified wood is 3.50 X 103 years old. What is the rate of decay, in counts per minute per gram, of carbon-14 in the sample? The decay rate of carbon-14 in wood today is 13.6 counts per minute per gram, and the half life of carbon-14 is 5730 years.



For a first order reaction the rate R = 鈭択 N?

Since radioactive decay is a first order reaction, use the equation:



ln(N/No)= -kt (you%26#039;re looking for N since No is already given as 13.6.)



First, find the decay constant : 0.693/(half-life of C-14)



0.693/5730=



1.20942E-4



Next, multiply the decay constant (negative as stated by first order reaction equation) by the age of the tree:



-(1.20942E-4)(3500)=



-.4232984293



Now you are left with:



ln(N/13.6) = -.4232984293



Negate the natural log by %26quot;e-ing%26quot; it:



e^(ln (N/13.6) = e^(-.4232984293)



This will leave:



N/13.6 = .6548831676



Finally, solve for N which should be : 8.906411079



For a first order reaction the rate R = 鈭択 N?

R/13.6 = 3500/5730. Solve for R.

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